Argentometric titration. Definition: The process of determining the quantity of a sample by adding measured increments of a titrant until the end-point, at which. automatic titrator will be used to perform the titration, and to obtain the titration curve. Background. Argentometric Titrations. In order for a titrimetric method to be . A titration in which Ag+ is the titrant is called an argentometric titration. Table provides a list of several typical precipitation titrations.

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Because Tittations 4 2— imparts a yellow color to the solution, which might obscure the end point, only a small amount of K 2 CrO 4 is added. Post as a guest Name. An example of a lab procedure is here 2. In this section we demonstrate a simple method for sketching a precipitation titration curve.

A second type of indicator uses a species that forms a colored complex argentpmetric the titrant or the titrand.

Prior to the end-point of the titration, chloride ions remain in excess. They adsorb on the AgCl surface, imparting a negative charge to the particles.

Argentometric (silver nitrate) titrations overview

The stoichiometry of the reaction requires that. Before the end point, the precipitate of AgCl has a negative surface charge due to the adsorption of excess Cl —. A blank titration requires 0.


All chlorides are dissolved out of the residue, and titrated.

9.5: Precipitation Titrations

A further discussion of potentiometry is found in Chapter The blue line shows the complete titration curve. Quantitative chemical analysis 6th ed. It is also possible to use indirect argentometric methods for determination of anions, that create insoluble salts with silver I for example phosphate PO4, arsenate AsO4 and chromate CrO4.

Titration is in aqueous solution against a solution of silver nitrate of known concentration for silver I salts that give an insoluble precipitate. They are most often used for determination of chloride ions, but they can be used also for other halides bromide, iodide and some pseudohalides thiocyanate.

It is not suitable for titrating against chloride anions because it binds to AgCl more strongly than chloride does. Because dichlorofluoroscein also carries a negative charge, it is repelled by the precipitate and remains in solution where it has a greenish-yellow color.

A typical calculation is shown in the following example. Chemistry Stack Exchange works best with JavaScript enabled.


Although precipitation titrimetry is rarely listed as a standard method of analysis, it may still be useful titratioms a secondary analytical method for verifying other analytical methods. Precipitation titrations also can be extended to the analysis of mixtures provided that there is a ttirations difference in the solubilities of the precipitates.


Before the equivalence point, Cl — is present in excess and pCl is determined by the concentration of unreacted Argentomftric —. Waylander 5, 1 10 A better fit is possible if the two points before the equivalence point are further apart—for example, 0 mL and 20 mL— and the two points after the equivalence point are further apart.

Thus far we have examined titrimetric methods based on acid—base, complexation, and redox reactions. Typically, it is used to determine the amount of chloride present in a sample. The analysis for I — using the Volhard method requires a back titration.

Retrieved from ” https: Chloride ions react with silver I ions to give the insoluble silver chloride: There are two precipitates in this analysis: In the Fajans method, named after Kazimierz Fajanstypically dichlorofluorescein is used as an indicator; the end-point is marked by the green suspension turning pink. Views Read Edit View history.

To find the moles of titrant reacting with the sample, we first need to correct for the reagent blank; thus. Sign up using Facebook. A comparison of our sketch to the exact titration curve Figure 9.